Search results for "Speciation analysis"
showing 3 items of 3 documents
Recent Approaches for Chemical Speciation and Analysis by Electrospray Ionization (ESI) Mass Spectrometry
2021
In these latest years, the chemical speciation of several species has been increasingly monitored and investigated by means of electrospray ionization mass spectrometry (ES-MS). This soft ionization technique is capable to gently take into the gas phase metal-ligand complexes and gather a wealth of information on their energetics, shape, and fragmentation pathways. For this reason, this technique is frequently chosen in a synergistic approach to investigate competitive ligand exchange-adsorptive other ways analyzed by cathodic stripping voltammetry (CLE-ACSV). ESI-MS analyses require a careful experimental design as they may be impacted by instrumental artifacts such as ESI adduct formation…
The Impact of Humic Substances as Remediation Agents to the Speciation Forms of Metals in Soil
2013
Abstract Humic substances (HS) are the most widespread group of organic substances in natural environment and have high stability. The main terrestrial reserves are found in the form of naturally occurring ore, peat or lignite. The aim of this paper is to study possibilities to use HS as agents for remediation of contaminated with heavy metals soil and impacts of HS of metal speciation forms in it. It has been proved that HS are able to bind to metal ions and change their speciation forms in soils. The ability to form complexes with metal ions depends on the type of soil, type of metal, as well as concentrations of HS in soil. The study was carried out in experimental conditions and analyti…
Analysis of the Mobility of Heavy Metals in Sludge for the Sewage Treatment Plant in Daleszyce
2020
Osady ściekowe są produktem ubocznym procesów oczyszczania ścieków. Wykazują jednak wysokie właściwości nawo-zowe oraz glebotwórcze, jednak nie zawsze mogą być one wykorzystane w tym celu. Dwa główne kryteria ograniczające ich przyrodnicze wykorzystanie to zawartość metali ciężkich oraz jaj pasożytów. Osady ściekowe pobrane z oczyszczalni ścieków w Daleszycach zostały poddane analizie zawartości metali ciężkich. W tym celu wykonano analizę specjacyjną, pozwalającą podzielić całkowitą zawartość metali na cztery frakcje mobilności. Mobilność określa zdolność pierwiastka, lub któregoś z jego form, do przemieszczania się w środowisku. Badania wykonano, stosując czteroetapową procedurę BCR. Wyni…